Answer:
You can't return the ACH entry; it's more than 60 days old now (in March 2021). You could attempt to reach out to the ODFI to request a later return. You definitely have no standing to do that, though, since the payment back in September was apparently authorized. You might try contacting the bank that accepted the check for deposit for the posting in January. But I don't think your prospects for a reimbursement are very good.
Does your bank not have a front-end that checks for previous payments of the same serial number on an account?