Acceptable forms of identification include
driver’s license, military and military/dependent
identification cards, passport, state issued identification
card, cedular card (foreign), non-resident alien
identification cards, or any other identification document
or documents, which contain name and preferably
address and a photograph and are normally acceptable
by financial institutions as a means of identification when
cashing checks for persons other than established
customers.
That's the description of acceptable ID forms from the FinCEN Form 104 (CTR). If your bank accepts a Matricula card for check cashing, it should be acceptable for item 14 on Form 104, since it meets that description.