Personal opinion: You need to think it likely that your customer started out with more than $10K in cash and broke it down for the sole purpose of avoiding the CTR before "structuring" is a reasonable accusation. I'm trying not to be overly persuaded by the odd dollars and odd cents, but your numbers alone do not give me a "structuring" vibe.
Regardless, as noted, you have the basis for asking a consumer customer: Whussup? regarding the source of the cash. I've heard both credible and incredible explanations of similar activity. Also as noted, sometimes you are looking at business, not consumer, activity and the account relationship needs to be revised.
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In this world you must be oh so smart or oh so pleasant. Well, for years I was smart. I recommend pleasant.